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Yttrium chloride
[CAS# 10361-92-9]

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Identification
ClassificationInorganic chemical industry >> Inorganic salt >> Metal halides and halides >> Metal chlorides and salts
NameYttrium chloride
SynonymsYttrium trichloride; Yttrium(III) chloride
Molecular StructureCAS # 10361-92-9, Yttrium chloride
Molecular FormulaYCl3
Molecular Weight195.26
CAS Registry Number10361-92-9
EC Number233-801-0
SMILES[Cl-].[Cl-].[Cl-].[Y+3]
Properties
Density2.67 g/mL (25 °C)
Melting point360 °C*
*Korshunov, B. G.
Safety Data
Hazard Symbolssymbol symbol symbol   GHS05;GHS07;GHS09 Danger  Details
Risk StatementsH317-H318-H410  Details
Safety StatementsP261-P272-P273-P280-P302+P352-P305+P351+P338  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Eye irritationEye Irrit.2H319
Skin irritationSkin Irrit.2H315
Specific target organ toxicity - single exposureSTOT SE3H335
Serious eye damageEye Dam.1H318
Acute hazardous to the aquatic environmentAquatic Acute1H400
Skin sensitizationSkin Sens.1BH317
Chronic hazardous to the aquatic environmentAquatic Chronic1H410
Acute toxicityAcute Tox.4H312
Acute toxicityAcute Tox.4H302
Acute toxicityAcute Tox.4H332
Skin sensitizationSkin Sens.1H317
Chronic hazardous to the aquatic environmentAquatic Chronic2H411
Substances or mixtures corrosive to metalsMet. Corr.1H290
SDSAvailable
up Discovery and Applications
Yttrium chloride (YCl3) is an important compound in the field of inorganic chemistry. It appears as a white to pale yellow crystalline solid that is soluble in water, ethanol, and hydrochloric acid. It is hygroscopic, with a melting point of about 721°C and a boiling point of about 1,500°C. It forms hydrates in aqueous solutions, usually in the form of YCl₃·6H₂O. Yttrium was discovered in 1794 by Finnish chemist Johan Gadolin while analyzing yttrium ore in Ytterby, Sweden. As researchers explored the reactivity and utility of yttrium in various chemical processes, yttrium chloride also gained attention as a versatile compound that can be used in both laboratory and industrial applications.

Yttrium chloride can be used as a catalyst for polymerization reactions, especially in the production of polyolefins. It promotes the formation of long-chain molecules and is valuable in the manufacture of plastics and synthetic rubbers. Yttrium chloride is used as a Lewis acid catalyst in organic synthesis, facilitating reactions such as Friedel-Crafts alkylation and acylation, which are essential for the generation of complex organic compounds.

Yttrium chloride is used to make advanced ceramics. Yttrium chloride is key to the production of yttria-stabilized zirconia (YSZ), a material known for its high-temperature stability and ionic conductivity, which is used in fuel cells and thermal barrier coatings. Yttrium chloride is used to produce yttrium aluminum garnet (YAG) and other optical materials. These materials are key ingredients in lasers, phosphors, and optical devices that provide high efficiency and durability.

Yttrium chloride is added to phosphors used in cathode ray tubes (CRTs), LED displays, and fluorescent lamps. Yttrium chloride has aided the development of red phosphors, improving the color quality and brightness of electronic displays.

Yttrium chloride is used in the synthesis of high-temperature superconducting materials, such as YBa₂Cu₃O₇ (YBCO). These materials exhibit superconductivity at relatively high temperatures and are expected to have applications in energy transmission and magnetic levitation. Yttrium chloride is used in nuclear science because of its neutron absorption properties. Yttrium chloride is studied for use in nuclear reactors and radiation shielding materials.

Yttrium chloride is used to produce specialized metal alloys. Yttrium enhances the properties of metals, including aluminum and magnesium alloys, by improving strength, corrosion resistance, and thermal stability. These alloys are important in the aerospace and automotive industries.

Yttrium chloride is used as a reagent in a variety of chemical syntheses, including the preparation of yttrium complexes and coordination compounds. Its reactivity with organic and inorganic substrates makes it widely used in laboratory research.

References

1998. Effects of intratracheal pretreatment with yttrium chloride (YCl3) on inflammatory responses of the rat lung following intratracheal instillation of YCl3. Toxicology Letters, 97(2).
DOI: 10.1016/s0378-4274(98)00137-4

2017. YCl3 Promotes Neuronal Cell Death by Inducing Apoptotic Pathways in Rats. BioMed Research International.
DOI: 10.1155/2017/2183658

2023. Yttrium chloride induces ferroptosis in cardiomyocytes via iron accumulation and triggers cardiac lipid peroxidation and inflammation that cause heart adverse events in mice. Ecotoxicology and Environmental Safety, 263.
DOI: 10.1016/j.ecoenv.2023.115279
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