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2-Methylfuran
[CAS# 534-22-5]

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Identification
ClassificationChemical pesticide >> Insecticide intermediate
Name2-Methylfuran
SynonymsSilvan
Molecular StructureCAS # 534-22-5, 2-Methylfuran
Molecular FormulaC5H6O
Molecular Weight82.10
CAS Registry Number534-22-5
EC Number208-594-5
SMILESCC1=CC=CO1
Properties
Density0.91 g/mL (Expl.)
Melting point-88.7 °C (Expl.)
Boiling point63-66 °C (Expl.)
Refractive index1.433 (Expl.)
Flash point-26 °C (Expl.)
Water solubility0.3 g/100 mL (20 °C) (Expl.)
Safety Data
Hazard Symbolssymbol symbol symbol symbol   GHS02;GHS06;GHS07;GHS09 Danger  Details
Risk StatementsH225-H301-H319-H330-H331-H411  Details
Safety StatementsP210-P233-P240-P241-P242-P243-P260-P261-P264-P264+P265-P270-P271-P273-P280-P284-P301+P316-P303+P361+P353-P304+P340-P305+P351+P338-P316-P320-P321-P330-P337+P317-P370+P378-P391-P403+P233-P403+P235-P405-P501  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Flammable liquidsFlam. Liq.2H225
Acute toxicityAcute Tox.3H301
Acute toxicityAcute Tox.3H331
Eye irritationEye Irrit.2H319
Acute toxicityAcute Tox.2H330
Specific target organ toxicity - repeated exposureSTOT RE2H373
Skin irritationSkin Irrit.2H315
Acute toxicityAcute Tox.4H312
Transport InformationUN 2301
SDSAvailable
up Discovery and Applications
2-Methylfuran is a chemical compound that belongs to the furan family, which consists of heterocyclic compounds with a five-membered ring containing four carbon atoms and one oxygen atom. 2-Methylfuran is characterized by a methyl group (-CH3) attached to the second position of the furan ring, giving it a distinctive structure compared to its parent compound, furan. This compound has garnered attention for its potential applications in both industrial processes and as a biofuel, owing to its unique chemical properties and renewable production methods.

The discovery of 2-methylfuran can be traced back to the mid-20th century when scientists were actively exploring the reactivity and synthesis of substituted furans. The methylation of furan, a relatively simple reaction, was one of the early strategies employed to produce substituted furan compounds like 2-methylfuran. Researchers were particularly interested in this class of compounds due to their potential for use in solvents, fragrances, and as intermediates in the synthesis of pharmaceuticals and other fine chemicals.

One of the key applications of 2-methylfuran is as a biofuel or biofuel additive. As part of the ongoing search for sustainable and renewable energy sources, 2-methylfuran has attracted attention as a potential alternative to gasoline. It can be derived from biomass, particularly from sugars present in plant materials, through catalytic processes that convert sugars into furan-based compounds. Due to its high energy content and favorable combustion properties, 2-methylfuran can be used as a blend component in gasoline or as a standalone fuel. Its use as a biofuel is particularly appealing because it is produced from renewable resources, and it has the potential to reduce dependence on fossil fuels, thereby contributing to the reduction of greenhouse gas emissions.

In addition to its use as a fuel, 2-methylfuran is employed as a solvent and intermediate in the chemical industry. The compound has good solubility properties and is used in the formulation of paints, coatings, and cleaning agents. Its relatively low polarity and ability to dissolve a range of organic compounds make it an attractive alternative to more toxic solvents, such as benzene or toluene, in some applications. Moreover, 2-methylfuran is also utilized in the synthesis of various chemicals, including pharmaceuticals, agrochemicals, and fragrances, where it serves as a starting material or intermediate in complex reactions.

Another important application of 2-methylfuran is in the field of materials science. Researchers have explored its potential as a precursor for the synthesis of advanced polymers and materials. The compound's reactive nature allows it to be polymerized into high-performance materials that may be used in the development of new coatings, adhesives, and other specialty materials. The sustainability of 2-methylfuran, when derived from renewable sources, further enhances its appeal for use in the creation of green materials and eco-friendly products.

The compound has also been investigated for its potential use in chemical processes, such as the production of fine chemicals and pharmaceuticals. As an intermediate in organic synthesis, 2-methylfuran can be involved in a range of reactions, such as nucleophilic substitutions, alkylations, and cycloadditions, to yield various valuable compounds. Its versatility in synthetic chemistry makes it a key building block for many industrial processes.

In conclusion, 2-methylfuran is a versatile and valuable chemical compound with a range of applications in industries such as energy, chemicals, and materials science. Its potential as a biofuel, solvent, and intermediate in chemical synthesis makes it an important component in the development of sustainable products and processes.

References

2021. Probing electrosynthetic reactions with furfural on copper surfaces. Chemical communications (Cambridge, England), 57(44).
DOI: 10.1039/d1cc01429c

2016. Conversion of Xylose to Furfuryl Alcohol and 2-Methylfuran in a Continuous Fixed-Bed Reactor. ChemSusChem, 9(8).
DOI: 10.1002/cssc.201600116
Market Analysis Reports
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