(3S,alphar)-3-[[[4-[(R)-3-Amino-3-Carboxypropoxy]Phenyl][(E)-Hydroxyimino]Acetyl]Amino]-alpha-(4-Hydroxyphenyl)-2-Oxo-1-Azetidineacetic Acid
[CAS# 60134-71-6]

Identification

• Name: (3S,alphar)-3-[[[4-[(R)-3-Amino-3-Carboxypropoxy]Phenyl][(E)-Hydroxyimino]Acetyl]Amino]-alpha-(4-Hydroxyphenyl)-2-Oxo-1-Azetidineacetic Acid
• Synonyms: 1-Azetidineacetic Acid, 3-(((4-(3-Amino-3-Carboxypropoxy)Phenyl)(Hydroxyimino)Acetyl)Amino)-Alpha-(4-Hydroxyphenyl)-2-Oxo-, (3S-(1(S*),3R*(Z(S*))))-; Antibiotic Fr 1923; Fr-1923-C
• Molecular Formula: C₂₃H₂₄N₄O₉
• Molecular Weight: 500.46
• CAS Registry Number: 60134-71-6
• SMILES: [C@@H]1(CN(C1=O)[C@@H](C(=O)O)C2=CC=C(C=C2)O)NC(C(=N/O)/C3=CC=C(C=C3)OCC[C@H](C(=O)O)N)=O
• InChI: 1S/C23H24N4O9/c24-16(22(31)32)9-10-36-15-7-3-12(4-8-15)18(26-35)20(29)25-17-11-27(21(17)30)19(23(33)34)13-1-5-14(28)6-2-13/h1-8,16-17,19,28,35H,9-11,24H2,(H,25,29)(H,31,32)(H,33,34)/b26-18+/t16-,17+,19-/m1/s1
• InChIKey: CTNZOGJNVIFEBA-TWTPMLPMSA-N

Properties

• Density: 1.571g/cm³ (Cal.)

References

• (1): Hodgson Simon T., Hollinshead David M., Ley Steven V., Low Caroline M. R., Williams David J.. Use of ?-allyltricarbonyliron lactam complexes in the preparation of nocardicin derivatives: synthesis of (?)-3-oxo-1-[(p-benzyloxyphenyl)-benzyloxycarbonylmethyl]azetidin-2-one, Journal of the Chemical Society, Perkin Transactions 1, 1985