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Hydrogen peroxide
[CAS# 7722-84-1]

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Identification
ClassificationInorganic chemical industry >> Inorganic salt >> Oxides and peroxides >> Non-metal oxides and peroxides
NameHydrogen peroxide
Molecular StructureCAS # 7722-84-1, Hydrogen peroxide
Molecular FormulaH2O2
Molecular Weight34.01
CAS Registry Number7722-84-1
EC Number231-765-0
SMILESOO
Properties
Solubilitymiscible (water), soluble (ethanol, ether) (Expl/)
Density1.4067 g/mL (25 °C) (Expl.)
Melting point-40 °C (Expl.)
Index of Refraction1.335 (Expl.)
Boiling point126 °C (Expl.)
Safety Data
Hazard Symbolssymbol symbol symbol   GHS03;GHS05;GHS07 Danger  Details
Risk StatementsH271-H302-H314-H318-H332-H335-H412  Details
Safety StatementsP210-P220-P260-P261-P264-P264+P265-P270-P271-P273-P280-P283-P301+P317-P301+P330+P331-P302+P361+P354-P304+P340-P305+P354+P338-P306+P360-P316-P317-P319-P321-P330-P363-P370+P378-P371+P380+P375-P403+P233-P405-P420-P501  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Skin corrosionSkin Corr.1AH314
Acute toxicityAcute Tox.4H302
Acute toxicityAcute Tox.4H332
Oxidising liquidsOx. Liq.1H271
Serious eye damageEye Dam.1H318
Specific target organ toxicity - single exposureSTOT SE3H335
Chronic hazardous to the aquatic environmentAquatic Chronic3H412
Oxidising liquidsOx. Liq.2H272
Acute toxicityAcute Tox.3H331
Skin corrosionSkin Corr.1BH314
Flammable liquidsFlam. Liq.2H225
Acute toxicityAcute Tox.4H312
Substances or mixtures corrosive to metalsMet. Corr.1H290
Chronic hazardous to the aquatic environmentAquatic Chronic2H411
Acute toxicityAcute Tox.3H301
Skin corrosionSkin Corr.1H314
Skin irritationSkin Irrit.2H315
Eye irritationEye Irrit.2H319
Acute toxicityAcute Tox.2H330
Transport InformationUN 2015; UN 2014; UN 2984
SDSAvailable
up Discovery and Applications
Hydrogen peroxide (H₂O₂) is a simple yet highly versatile chemical compound that has found a wide range of applications in various industries, from healthcare to manufacturing. It is a colorless liquid with strong oxidizing properties and is known for being a powerful disinfectant and bleaching agent. Hydrogen peroxide is typically produced by the autoxidation of anthraquinone or through electrochemical processes. Its discovery dates back to the early 19th century, and it has since become one of the most commonly used chemicals worldwide.

Hydrogen peroxide was first discovered in 1818 by the French chemist Louis-Jacques Thénard. Thénard obtained hydrogen peroxide by reacting barium peroxide with dilute acids. He was able to isolate the compound and demonstrated its chemical properties, including its ability to release oxygen when decomposed. The name "hydrogen peroxide" was derived from its molecular composition, with "hydrogen" representing the H atoms and "peroxide" referring to the presence of an oxygen-oxygen bond.

The compound's strong oxidizing properties were quickly recognized, and by the mid-19th century, hydrogen peroxide began to be used in a variety of applications. It gained popularity as a bleaching agent for textiles and paper, where its ability to break down color and organic materials was highly valued. This application continues today in industries like pulp and paper, where hydrogen peroxide is still widely used to bleach and brighten materials without the use of harsh chemicals like chlorine.

In the medical field, hydrogen peroxide's disinfectant properties have made it an important tool for sterilization and wound care. When applied to cuts and abrasions, hydrogen peroxide releases oxygen, which helps to clean the wound and kill bacteria. It is also used as a mouthwash and in dental care products, where it aids in the prevention of gum disease and tooth decay. However, its use as a wound disinfectant has been limited in recent years, as more research has shown that it can damage healthy tissue and slow down the healing process when used in high concentrations.

Hydrogen peroxide also plays a critical role in the field of environmental cleanup. Its oxidizing properties make it effective for breaking down pollutants in water and soil. For example, it is used in wastewater treatment to neutralize harmful substances and to purify water in industrial applications. Hydrogen peroxide is also used in the oil and gas industries for cleaning equipment and removing contaminants from water and oil.

In the chemical manufacturing industry, hydrogen peroxide is used in the production of a variety of products, including the synthesis of other chemicals such as peracetic acid, propylene oxide, and terephthalic acid. It serves as an environmentally friendly alternative to chlorine-based chemicals in many industrial processes. Moreover, hydrogen peroxide is used in the formulation of household cleaning products due to its efficacy in removing stains, disinfecting surfaces, and deodorizing.

The compound's versatility extends to its role as an oxidizing agent in a variety of other industries. Hydrogen peroxide is used in the production of semiconductors and electronics, where it plays a part in cleaning and etching processes. It is also used in rocket propulsion systems as a propellant due to its ability to release large amounts of oxygen when decomposed.

Despite its widespread use, hydrogen peroxide is a reactive chemical that requires careful handling. At higher concentrations, it can be corrosive, and its decomposition can release oxygen gas, which can cause pressure buildup in sealed containers. Consequently, hydrogen peroxide is often stabilized and stored in dark containers to prevent decomposition caused by light exposure.

In conclusion, hydrogen peroxide is a chemical compound with a rich history and a broad spectrum of applications. From its early use in bleaching and disinfecting to its current role in healthcare, environmental management, and chemical manufacturing, hydrogen peroxide has proven to be an invaluable substance. As research into its uses continues, new applications for hydrogen peroxide are likely to emerge, solidifying its place as one of the most widely used chemicals in the world.

References

1862. Ueber einige neuen höchst empfindlichen Reagentien auf das Wasserstoffsuperoxyd. Zeitschrift für analytische Chemie.
DOI: 10.1007/bf01430085

2025. Ingenious construction of a magnetic-recyclable photo-Fenton catalyst ZnFe2O4@MIL-88A(Fe) and its adsorption-degradation activity toward levofloxacin. Journal of environmental sciences (China), 147.
DOI: 10.1016/j.jes.2024.04.043

2025. Determination of persulfate based on the principle of the oxidation of chloride ion. Journal of environmental sciences (China), 146.
DOI: 10.1016/j.jes.2023.11.028
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