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Calcium sulfate
[CAS# 7778-18-9]

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Identification
ClassificationInorganic chemical industry >> Inorganic salt >> Metal sulfides and sulfates
NameCalcium sulfate
Molecular StructureCAS # 7778-18-9, Calcium sulfate
Molecular FormulaCaSO4
Molecular Weight136.14
CAS Registry Number7778-18-9
EC Number231-900-3
SMILES[O-]S(=O)(=O)[O-].[Ca+2]
Properties
Solubility0.162% w/w (water 100 °C)
Density2.96
Melting point1450 °C
Boiling point163 °C
Safety Data
Hazard Symbolssymbol symbol   GHS08;GHS09 Danger  Details
Risk StatementsH317-H319-H334-H341-H350-H360F-H411  Details
Safety StatementsP202-P273-P280-P302+P352-P305+P351+P338-P308+P313  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Skin irritationSkin Irrit.2H315
Serious eye damageEye Dam.1H318
Eye irritationEye Irrit.2H319
Specific target organ toxicity - single exposureSTOT SE3H335
SDSAvailable
up Discovery and Applications
Calcium sulfate, chemically CaSO4, is a versatile compound with various industrial, medical, and agricultural applications. Calcium sulfate has been known since ancient times for its presence in natural deposits and minerals. It is composed of calcium ions (Ca²?) and sulfate ions (SO4²?). The compound exists in a variety of forms, including gypsum (CaSO4·2H2O), which is the common hydrated form found in nature, and anhydrous gypsum (CaSO4), which is less common and usually found in dry environments.

Gypsum is the hydrated form of calcium sulfate and a key ingredient in building materials. It is used in gypsum board (drywall), cement, and plaster to improve fire resistance, sound insulation, and structural integrity. Gypsum board is widely used for interior walls and ceilings due to its ease of installation and durability. In the cement industry, calcium sulfate acts as a setting regulator and strength enhancer. It helps control the setting time of cement and improves its workability, contributing to the production of high-quality concrete and mortar used in construction projects around the world. Calcium sulfate is used as a soil conditioner to improve soil structure and fertility. Gypsum helps loosen compacted soil, enhance water penetration and root growth, and reduce nutrient loss. It is particularly beneficial to agricultural soils with high clay content.

Calcium sulfate is added to fertilizers as a source of calcium and sulfur, essential nutrients for plant growth and development. It helps improve soil pH balance, promotes root health, and increases crop yields, especially in areas where soil calcium levels are insufficient.

Calcium sulfate is used as a food additive in the food industry to adjust and enhance the texture of various products. It is used as a firming agent, stabilizer, and coagulant in foods such as tofu, baked goods, and dairy products. Calcium sulfate helps maintain product consistency and shelf life. In pharmaceutical formulations, calcium sulfate is used as a filler and binder in tablet manufacturing. Its inertness and compressibility make it suitable for ensuring uniform distribution of active ingredients and improving the mechanical properties of tablets.

Plaster of Paris is a hemihydrate of calcium sulfate that is used in orthopedic medicine to make casts and molds to immobilize broken bones and support injured limbs during healing. It solidifies quickly and forms strong, lightweight structures, making it ideal for medical applications.

References

1994. Immersion disinfection of irreversible hydrocolloid impressions with sodium hypochlorite. Part II: Effect on gypsum. The International journal of prosthodontics, 7(4).
URL: https://pubmed.ncbi.nlm.nih.gov/7993542

1987. Compatibility of type IV dental stones with polyvinyl siloxane impression materials. The Journal of Prosthetic Dentistry, 58(1).
DOI: 10.1016/s0022-3913(87)80136-1

1987. A comparison of abrasion resistance of dental stones. Dental materials : official publication of the Academy of Dental Materials, 3(2).
DOI: 10.1016/s0109-5641(87)80001-5
Market Analysis Reports
List of Reports Available for Calcium sulfate
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