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Sodium silicate
[CAS# 1344-09-8]

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Identification
ClassificationInorganic chemical industry >> Inorganic salt >> Silicide and silicate
NameSodium silicate
SynonymsSodium orthosilicate; Silicic acid sodium salt
Molecular StructureCAS # 1344-09-8, Sodium silicate
Molecular FormulaNa2SiO3
Molecular Weight122.06
CAS Registry Number1344-09-8
EC Number215-687-4
SMILES[O-][Si](=O)[O-].[Na+].[Na+]
Properties
Density1.39 g/mL (25 °C)
Safety Data
Hazard Symbolssymbol symbol   GHS05;GHS07 Danger  Details
Risk StatementsH290-H302-H314-H315-H318-H319-H335  Details
Safety StatementsP234-P260-P261-P264-P264+P265-P270-P271-P280-P301+P317-P301+P330+P331-P302+P352-P302+P361+P354-P304+P340-P305+P351+P338-P305+P354+P338-P316-P317-P319-P321-P330-P332+P317-P337+P317-P362+P364-P363-P390-P403+P233-P405-P406-P501  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Skin irritationSkin Irrit.2H315
Serious eye damageEye Dam.1H318
Specific target organ toxicity - single exposureSTOT SE3H335
Eye irritationEye Irrit.2H319
Acute toxicityAcute Tox.4H302
Skin corrosionSkin Corr.1BH314
Substances or mixtures corrosive to metalsMet. Corr.1H290
Skin corrosionSkin Corr.1AH314
Skin corrosionSkin Corr.1CH314
Specific target organ toxicity - single exposureSTOT SE3H336
Skin corrosionSkin Corr.1H314
Acute hazardous to the aquatic environmentAquatic Acute1H400
Chronic hazardous to the aquatic environmentAquatic Chronic1H410
Skin sensitizationSkin Sens.1H317
Acute toxicityAcute Tox.4H332
Eye irritationEye Irrit.2H318
CarcinogenicityCarc.1BH350
Acute toxicityAcute Tox.4H312
SDSAvailable
up Discovery and Applications
Sodium silicate, commonly known as waterglass or liquid glass, is an inorganic compound with the chemical formula Na2SiO3 or Na2Si2O5, depending on its specific form. Its discovery dates back to the 19th century, and early uses date back to the development of the first silicate glasses and cements. The compound was identified through the reaction of sodium carbonate with silica or sand, which produced a soluble form of silica that can be used in various industrial processes.

Sodium silicate is a widely used compound that is available in both solid and liquid forms. The solid form is usually a white or colorless glassy substance, while the liquid form is a clear, viscous solution. The compound is soluble in water to form an alkaline solution with a pH between 11 and 13. Sodium silicate is known for its adhesive properties, thermal stability, and ability to form gels and precipitates.

Sodium silicate is widely used in various industries due to its unique properties. In construction, sodium silicate acts as a binder and hardener in cement and concrete formulations. It improves the strength and durability of concrete by promoting the formation of a dense, impermeable structure. This application is particularly valuable in repairing and protecting concrete surfaces. Sodium silicate is an important ingredient in detergents and soaps. It acts as a builder, enhancing the effectiveness of surfactants by softening water and preventing the formation of insoluble soap scum. This improves the cleaning efficiency of household and industrial cleaning products. In the ceramic industry, sodium silicate is used as a dispersant in clay bodies, improving the flow and workability of ceramic materials. In glass manufacturing, it is used as a flux, lowering the melting temperature of silica and facilitating the production of various glass products.

Sodium silicate is used in water treatment processes. It helps remove impurities from water by enhancing the coagulation and flocculation processes. Sodium silicate helps form larger flocs from suspended particles, which can then be easily removed by sedimentation or filtration. In industrial water systems, sodium silicate is used as a corrosion inhibitor. It forms a protective layer on metal surfaces, reducing the rate of corrosion and extending the service life of equipment.

Sodium silicate-based products are used in fire-resistant coatings and treatments for building materials. These coatings form a protective layer that can withstand high temperatures, enhancing the fire resistance of structures and materials.

In the textile industry, sodium silicate is used in dyeing and printing processes. It acts as a mordant, helping to fix dyes to fabrics and improve color fastness. Sodium silicate is used as a flotation agent in the mining industry, helping to separate valuable minerals from ores.

Handling sodium silicate requires proper safety measures, using gloves, goggles, and protective clothing, and avoiding direct contact with the compound. Inhalation of dust or vapors should be avoided, and work areas should be well ventilated. Store sodium silicate in sealed containers in a cool, dry place to prevent moisture absorption and chemical degradation.

The environmental impact of sodium silicate is generally manageable. The compound is not biodegradable, but is inert in the environment. It should be used and disposed of in accordance with environmental regulations to minimize potential impacts to aquatic systems and soil. Proper handling and disposal methods can help mitigate any environmental risks associated with sodium silicate.

References

2003. Silica-alginate composites for microencapsulation. Applied Microbiology and Biotechnology, 61(5-6).
DOI: 10.1007/s00253-003-1308-5

2015. Optimization of NaOH Molarity, LUSI Mud/Alkaline Activator, and Na2SiO3/NaOH Ratio to Produce Lightweight Aggregate-Based Geopolymer. International Journal of Molecular Sciences, 16(5).
DOI: 10.3390/ijms160511629

2024. Synthesis, Characterization, and Antibacterial Studies of Nickel-Silica Nanoparticles. Chemistry Africa, 7(12).
DOI: 10.1007/s42250-024-01153-4
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