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Calcium acetylacetonate
[CAS# 19372-44-2]

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Identification
ClassificationOrganic raw materials >> Organometallic compound >> Organic calcium
NameCalcium acetylacetonate
SynonymsCalcium 2,4-pentanedionate
Molecular StructureCAS # 19372-44-2, Calcium acetylacetonate
Molecular FormulaC10H14CaO4
Molecular Weight238.30
CAS Registry Number19372-44-2
EC Number243-001-3
SMILESC/C(=C/C(=O)C)/[O-].C/C(=C/C(=O)C)/[O-].[Ca+2]
Properties
Melting point175 °C
Safety Data
Hazard Symbolssymbol symbol symbol   GHS05;GHS07;GHS08 Danger  Details
Risk StatementsH302-H315-H317-H318-H319-H335-H361  Details
Safety StatementsP203-P261-P264-P264+P265-P270-P271-P272-P280-P301+P317-P302+P352-P304+P340-P305+P351+P338-P305+P354+P338-P317-P318-P319-P321-P330-P332+P317-P333+P317-P337+P317-P362+P364-P403+P233-P405-P501  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Acute toxicityAcute Tox.4H302
Serious eye damageEye Dam.1H318
Skin sensitizationSkin Sens.1AH317
Eye irritationEye Irrit.2H319
Skin sensitizationSkin Sens.1H317
Skin irritationSkin Irrit.2H315
Reproductive toxicityRepr.2H361
Specific target organ toxicity - single exposureSTOT SE3H335
Acute toxicityAcute Tox.4H312
Acute toxicityAcute Tox.3H331
Acute toxicityAcute Tox.3H311
Acute toxicityAcute Tox.4H332
Skin sensitizationSkin Sens.1BH317
SDSAvailable
up Discovery and Applications
Calcium acetylacetonate is an organometallic compound with the chemical formula Ca(C5H7O2)2. It is part of the larger family of acetylacetonate complexes, which are well-known for their ability to form stable chelate structures with various metal ions. The discovery of calcium acetylacetonate dates back to the mid-20th century when chemists began to investigate the coordination chemistry of acetylacetone and its derivatives. The compound is synthesized through the reaction of calcium salts, such as calcium chloride, with acetylacetone in the presence of a suitable solvent, typically yielding a bright yellow powder.

Calcium acetylacetonate exhibits several unique properties, including thermal stability and solubility in organic solvents, which contribute to its versatility in various applications. One of the primary applications of calcium acetylacetonate is as a precursor in the synthesis of calcium oxide (CaO) and calcium hydroxide (Ca(OH)2). These compounds are vital in various industrial processes, including the production of glass, ceramics, and paper.

In addition to its role as a precursor, calcium acetylacetonate is also utilized as a catalyst in organic reactions. Its ability to coordinate with different substrates enables it to promote various chemical transformations, such as polymerization and condensation reactions. This catalytic property has garnered attention in research focused on developing more efficient and sustainable chemical processes.

The compound is also studied for its potential applications in the field of materials science. Calcium acetylacetonate can serve as a source of calcium ions in the synthesis of calcium-containing nanomaterials, which have implications in areas such as biomedicine, drug delivery, and environmental remediation. Its use in developing calcium-based composite materials, such as calcium silicate and calcium phosphate, has also been explored, given their applications in bone repair and tissue engineering.

Moreover, calcium acetylacetonate is of interest in the field of coordination chemistry. Its chelating ability with metal ions allows it to stabilize various metal complexes, which can be applied in catalysis, sensors, and electronic materials. Research is ongoing to explore its interactions with different metal ions and to develop new applications based on these complexes.

Despite its promising applications, the use of calcium acetylacetonate necessitates careful handling and consideration of safety protocols. As with many organometallic compounds, understanding its toxicity and environmental impact is crucial for ensuring its safe use in industrial and research settings.

In conclusion, calcium acetylacetonate is a significant chemical compound with diverse applications in various fields, including catalysis, materials science, and organic synthesis. Its discovery has paved the way for advancements in coordination chemistry and the development of innovative materials. Continued research into its properties and applications may yield further insights and potential uses in future scientific endeavors.

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