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Calcium acetate monohydrate
[CAS# 5743-26-0]

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Identification
ClassificationOrganic raw materials >> Organometallic compound >> Organic calcium
NameCalcium acetate monohydrate
SynonymsAcetic acid calcium salt monohydrate
Molecular StructureCAS # 5743-26-0, Calcium acetate monohydrate
Molecular FormulaC4H6CaO4.H2O
Molecular Weight176.18
CAS Registry Number5743-26-0
EC Number611-528-1
SMILESCC(=O)[O-].CC(=O)[O-].O.[Ca+2]
Properties
Density1.5 g/mL (Expl.)
Decomposition160 °C
Water solubilitysoluble (Expl.)
Safety Data
Hazard Symbolssymbol   GHS07 Warning  Details
Risk StatementsH302-H315-H319-H335  Details
Safety StatementsP261-P301+P312-P302+P352-P304+P340-P305+P351+P338  Details
SDSAvailable
up Discovery and Applications
Calcium acetate monohydrate, known chemically as Ca(C₂H₃O₂)₂·H₂O, is a calcium salt of acetic acid with notable uses in medical, industrial, and environmental applications. This compound, typically a white crystalline powder, became widely recognized in the 19th century when calcium salts began to be used for various medicinal and industrial purposes. The monohydrate form of calcium acetate is particularly valued for its stability, solubility in water, and ease of use in both solid and dissolved forms, making it suitable for multiple fields.

One of the most significant uses of calcium acetate monohydrate is in the medical field, particularly in the treatment of hyperphosphatemia—elevated phosphate levels in the blood. This condition often occurs in patients with chronic kidney disease, as the kidneys lose the ability to effectively filter phosphates. Calcium acetate acts as a phosphate binder, which means it binds with dietary phosphate in the digestive tract to form insoluble compounds that are excreted rather than absorbed. This process helps reduce serum phosphate levels, protecting patients from potential complications, including cardiovascular disease and bone disorders. As a result, calcium acetate monohydrate is commonly prescribed to patients with renal failure to help regulate their phosphate levels and maintain bone health.

In addition to its medical applications, calcium acetate monohydrate is widely used in the food industry as a stabilizer and preservative. It is commonly added to foods to prevent microbial growth, thereby extending shelf life. In baking, calcium acetate acts as a buffer, helping maintain consistent pH levels in products such as bread and cakes, which improves texture and preserves quality. This additive is generally recognized as safe (GRAS) by food regulatory agencies, allowing it to be used in various food products.

Calcium acetate monohydrate also finds application in industrial settings. In the textile industry, it is used as a mordant—a substance that binds dyes to fabrics to enhance colorfastness. The acetate group in calcium acetate binds well with dye molecules, helping them adhere more strongly to fibers. This results in brighter, more durable colors in dyed fabrics. The compound is also utilized in chemical manufacturing as a source of acetates, which are important reagents in organic synthesis. Calcium acetate’s ability to decompose to form acetone, a valuable solvent, is particularly useful in producing acetone on a small scale.

Another key application of calcium acetate monohydrate is in environmental management, specifically for wastewater treatment. It is used in processes to precipitate heavy metals and other contaminants from wastewater, aiding in their removal from industrial effluents before they are discharged into the environment. Calcium acetate’s capacity to act as a buffer and adjust pH levels in treatment systems makes it valuable in these settings, helping reduce pollution and environmental impact.

A lesser-known but historically relevant application of calcium acetate monohydrate involves its use in creating “calcium acetate fire” or "acetate candles." When mixed with ethanol, calcium acetate forms a gel-like substance that can be ignited and used as a stable, portable source of heat and light. This property has been utilized in portable cooking and heating devices, particularly in camping and emergency preparedness settings, where a smokeless flame source is advantageous.

Overall, calcium acetate monohydrate is a versatile compound with a range of applications in medicine, food preservation, textiles, environmental protection, and even in practical fire-starting kits. Its relatively low toxicity and ease of handling make it a preferred choice in these diverse fields.

References

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