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Sodium oxalate
[CAS# 62-76-0]

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Identification
ClassificationOrganic raw materials >> Carboxylic compounds and derivatives >> Carboxylic esters and their derivatives
NameSodium oxalate
SynonymsDisodium oxalate; Oxalic acid disodium salt; Ethanedioic acid sodium salt
Molecular StructureCAS # 62-76-0, Sodium oxalate
Molecular FormulaNa2C2O4
Molecular Weight134.00
CAS Registry Number62-76-0
EC Number200-550-3
SMILESC(=O)(C(=O)[O-])[O-].[Na+].[Na+]
Properties
Density2.34 g/mL
Melting point250-270 °C
Boiling point450 °C
Water solubility37 g/L (20 °C)
Safety Data
Hazard Symbolssymbol   GHS07 Warning  Details
Risk StatementsH302-H312  Details
Safety StatementsP264-P270-P280-P301+P317-P302+P352-P317-P321-P330-P362+P364-P501  Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Acute toxicityAcute Tox.4H312
Acute toxicityAcute Tox.4H302
Eye irritationEye Irrit.2H319
Acute toxicityAcute Tox.3H301
Acute toxicityAcute Tox.4H332
Skin irritationSkin Irrit.2H315
Specific target organ toxicity - single exposureSTOT SE3H335
Transport InformationUN 2449; UN 1759
SDSAvailable
up Discovery and Applications
Sodium oxalate, with the chemical formula Na2C2O4, is a white, crystalline compound commonly used in various industrial and laboratory applications. It is a salt derived from oxalic acid and is known for its ability to form stable complexes with metal ions. The discovery of sodium oxalate can be traced back to the early 19th century when chemists began to isolate and study organic acids and their salts. It was first prepared by the neutralization of oxalic acid with sodium carbonate, a process that laid the groundwork for its later applications.

Sodium oxalate is widely utilized in the textile industry, where it serves as a bleaching agent and a mordant in dyeing processes. Its ability to complex with metal ions is particularly useful in binding dyes to fabrics, improving the colorfastness and overall quality of dyed materials. Additionally, sodium oxalate finds application in the food industry as a food additive, where it is employed as an acidity regulator and stabilizer in certain food products.

In the field of chemistry, sodium oxalate is often used as a primary standard for determining the concentration of alkaline solutions in titrations. Its stable and well-defined properties make it an ideal candidate for use in analytical chemistry, particularly in laboratories focusing on quantitative analysis. The compound can also be used in the preparation of other oxalate salts, which have their own specific applications in various chemical processes.

Moreover, sodium oxalate has been studied for its potential role in various biological systems. Research has indicated that sodium oxalate can act as a chelating agent, binding to calcium ions and affecting calcium metabolism in biological organisms. This property has implications for both environmental science and medicine, particularly concerning calcium-related disorders and the behavior of heavy metals in ecological systems.

Despite its usefulness, sodium oxalate must be handled with care due to its toxicity. Ingestion of large amounts can lead to oxalate poisoning, characterized by symptoms such as nausea, vomiting, and abdominal pain. This necessitates the establishment of safety guidelines and regulations concerning its use, particularly in industrial settings and laboratories.

In conclusion, sodium oxalate is a versatile chemical compound with a rich history and a wide range of applications in textiles, food processing, and analytical chemistry. Its ability to form complexes with metal ions, along with its utility as a primary standard in titrations, underscores its importance in various scientific and industrial fields. Ongoing research continues to explore its role in biological systems and its potential environmental impacts.

References

1984. Absorption kinetics of oxalate from oxalate-rich food in man. The American Journal of Clinical Nutrition, 40(5).
DOI: 10.1093/ajcn/40.5.1007

2003. Effects of EDTA and low molecular weight organic acids on soil solution properties of a heavy metal polluted soil. Chemosphere, 50(6).
DOI: 10.1016/s0045-6535(02)00225-4

2024. Oxalate, Glycolate, and Glycerate. Laboratory Guide to the Methods in Biochemical Genetics.
DOI: 10.1007/978-3-031-58819-8_21
Market Analysis Reports
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