Iridium(III) chloride hydrate
[CAS# 14996-61-3]

Identification

• Classification: Inorganic chemical industry >> Inorganic salt >> Metal halides and halides >> Metal chlorides and salts
• Name: Iridium(III) chloride hydrate
• Molecular Formula: IrCl₃^.H₂O
• Molecular Weight: 316.59
• CAS Registry Number: 14996-61-3
• EC Number: 628-578-5
• SMILES: O.Cl[Ir](Cl)Cl

Properties

• Density: 5.3 g/mL (25 ºC) (Expl.)

Safety Data

• Hazard Symbols: GHS07 Warning
• Hazard Statements: H315-H319-H335
• Precautionary Statements: P261-P264-P264+P265-P271-P280-P302+P352-P304+P340-P305+P351+P338-P319-P321-P332+P317-P337+P317-P362+P364-P403+P233-P405-P501

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Skin irritation	Skin Irrit.	2	H315
Eye irritation	Eye Irrit.	2	H319
Specific target organ toxicity - single exposure	STOT SE	3	H335

Discovory and Applicatios

Iridium(III) chloride hydrate is an inorganic compound commonly represented by the formula IrCl₃·xH₂O, where the number of water molecules (x) varies depending on the preparation and hydration conditions. It typically appears as a dark green to black solid and is sparingly soluble in water, forming acidic solutions.

The compound is generally prepared by dissolving elemental iridium or iridium alloys in a mixture of hydrochloric acid and oxidizing agents such as chlorine gas or aqua regia, followed by crystallization from aqueous media. The resulting iridium(III) chloride hydrate contains iridium ions in the +3 oxidation state, coordinated by chloride ions and water molecules. Structurally, the solid form is often polymeric, featuring octahedral coordination of iridium centers bonded to chloride and water ligands. In solution, a variety of aqua and chloro complexes coexist depending on the acidity and chloride concentration.

Iridium(III) chloride hydrate serves as a key precursor in the synthesis of numerous iridium complexes utilized in catalysis, materials science, and coordination chemistry. It is employed extensively as a starting material for homogeneous catalysts in hydrogenation, hydroformylation, and carbonylation reactions. Transition metal complexes derived from iridium(III) chloride hydrate often display high activity and selectivity, especially in asymmetric catalytic processes.

In particular, iridium(III) chloride hydrate is the precursor to commercially important catalysts such as Crabtree's catalyst and various phosphine-ligated iridium complexes. These catalysts are notable for their ability to activate molecular hydrogen and facilitate the hydrogenation of olefins, dienes, and functionalized substrates under mild conditions. Additionally, the compound is used in preparing catalysts for water oxidation and transfer hydrogenation in green chemistry applications.

Beyond catalysis, iridium(III) chloride hydrate is also used to synthesize iridium-based materials for electronic and optical applications. It serves as a precursor in the preparation of iridium oxide thin films, which are valued for their conductivity, corrosion resistance, and electrochemical properties, making them useful in sensors, fuel cells, and electrochromic devices.

Handling of iridium(III) chloride hydrate requires standard laboratory safety precautions. It should be stored in tightly sealed containers, away from reducing agents and incompatible materials. While iridium compounds generally exhibit low toxicity, inhalation or prolonged exposure should be avoided, and appropriate protective equipment such as gloves and goggles should be used.

In summary, iridium(III) chloride hydrate is a dark crystalline solid comprising iridium in the +3 oxidation state coordinated by chloride and water ligands. It is a versatile precursor widely used in the preparation of catalytic complexes and advanced materials with applications spanning homogeneous catalysis, green chemistry, and electronic devices.

References

2020. Investigation of photophysical, electrochemical and electroluminescent properties of Iridium(III)bis[2-phenylbenzo[d]thiazolato-N,C2']-quinolin-8-olate for white organic light-emitting diodes application. Journal of Materials Science: Materials in Electronics, 31(16).
DOI: 10.1007/s10854-020-04133-9

2021. New iridium bis-terpyridine complexes: synthesis, characterization, antibiofilm and anticancer potentials. Biometals, 34(4).
DOI: 10.1007/s10534-021-00307-y

2022. Supramolecular Phosphorescent Polymer Based on Cationic Iridium Complexes for Polymer Light-Emitting Diodes. Journal of Inorganic and Organometallic Polymers and Materials, 32(1).
DOI: 10.1007/s10904-021-02211-x