Potassium chloroplatinate
[CAS# 16921-30-5]

Identification

• Classification: Analytical chemistry >> Analytical reagent >> Common analytical reagents
• Name: Potassium chloroplatinate
• Synonyms: Potassium hexachloroplatinate(IV)
• Molecular Formula: K₂PtCl₆
• Molecular Weight: 485.98
• CAS Registry Number: 16921-30-5
• EC Number: 240-979-3
• SMILES: Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.[K+].[K+]

Properties

• Density: 3.499 g/mL
• Melting point: 250 ºC
• Water solubility: 50 g/L (95 ºC)

Safety Data

• Hazard Symbols: GHS05;GHS06;GHS08 Danger
• Hazard Statements: H301-H317:-H318:-H334:
• Precautionary Statements: P233-P260-P261-P264-P264+P265-P270-P271-P272-P280-P284-P301+P316-P302+P352-P304+P340-P305+P354+P338-P317-P321-P330-P333+P317-P342+P316-P362+P364-P403-P405-P501

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Serious eye damage	Eye Dam.	1	H318
Respiratory sensitization	Resp. Sens.	1	H334
Skin sensitization	Skin Sens.	1	H317
Chronic hazardous to the aquatic environment	Aquatic Chronic	1	H410
Acute hazardous to the aquatic environment	Aquatic Acute	1	H400
Acute toxicity	Acute Tox.	2	H300
Acute toxicity	Acute Tox.	3	H301
Substances or mixtures corrosive to metals	Met. Corr.	1	H290
Skin sensitization	Skin Sens.	1B	H317
Respiratory sensitization	Resp. Sens.	1A	H334
Specific target organ toxicity - repeated exposure	STOT RE	1	H372

• Transport Information: UN 3290

Discovory and Applicatios

Potassium chloroplatinate is an inorganic coordination compound with the chemical formula K₂PtCl₆. It consists of the hexachloroplatinate(IV) anion, \[PtCl₆]²⁻, and two potassium cations, K⁺, that balance the charge. This compound is part of the platinum group halide salts and typically appears as bright yellow or orange crystalline solids, which are sparingly soluble in water and insoluble in most organic solvents. Potassium chloroplatinate is important both in industrial platinum refining and in research due to its well-defined coordination chemistry and stability.

The synthesis of potassium chloroplatinate is closely linked to the extraction and purification of platinum from ores or recycled materials. Platinum is commonly dissolved in aqua regia, a mixture of nitric acid and hydrochloric acid, to produce chloroplatinic acid (H₂PtCl₆). When aqueous solutions containing chloroplatinic acid are treated with potassium chloride or potassium ions under suitable conditions, potassium chloroplatinate precipitates as a solid. This precipitation reaction is highly selective for the hexachloroplatinate complex, enabling the isolation of platinum from complex mixtures of metals and impurities.

Structurally, potassium chloroplatinate contains the octahedral hexachloroplatinate(IV) anion, where a platinum(IV) ion is coordinated by six chloride ligands arranged symmetrically. The potassium ions act as counterions, providing charge balance and forming an ionic lattice with the complex anions in the crystalline state. This arrangement imparts notable thermal stability to the compound and influences its physical properties such as color, solubility, and melting point.

Potassium chloroplatinate serves several important roles in platinum chemistry. One of its primary uses is as an intermediate or precursor for the production of pure platinum metal. Thermal decomposition of K₂PtCl₆ at elevated temperatures leads to the formation of finely divided platinum metal, which is widely utilized in catalytic applications, electronic devices, and jewelry manufacturing. The high purity and controlled particle size of platinum obtained through this route make it especially valuable.

In research and industry, potassium chloroplatinate is also employed in the preparation of various platinum complexes through ligand substitution reactions. The hexachloroplatinate ion can undergo displacement of chloride ligands by phosphines, amines, or other ligands to form complexes with tailored electronic and catalytic properties. Such complexes are integral to homogeneous catalysis, facilitating important transformations like hydrogenation, oxidation, and carbon–carbon coupling reactions. These catalytic processes are essential in the production of fine chemicals, pharmaceuticals, and polymers.

In addition to its catalytic and metallurgical applications, potassium chloroplatinate is used in analytical chemistry. Its precipitation reaction with potassium ions provides a classical qualitative test for platinum in solution. The compound’s distinctive color and crystalline form allow for straightforward identification and quantification of platinum content in various samples, including ores, alloys, and industrial wastes.

Potassium chloroplatinate is generally stable under normal laboratory conditions but should be stored away from reducing agents and incompatible materials to prevent decomposition. While it exhibits low volatility and is not highly toxic in solid form, proper handling procedures should be followed to avoid inhalation or ingestion of dust, as platinum compounds can pose health risks. Use of personal protective equipment such as gloves, lab coats, and safety glasses is recommended when working with this compound.

The environmental and economic importance of potassium chloroplatinate is considerable, given the value of platinum and its critical role in modern technology. Efficient recovery and recycling processes often rely on potassium chloroplatinate as an intermediate, minimizing the need for new platinum mining and reducing associated environmental impacts.

In summary, potassium chloroplatinate is a bright yellow crystalline inorganic salt composed of potassium cations and the octahedral hexachloroplatinate(IV) anion. It plays a central role in platinum refining, catalyst preparation, and analytical chemistry. Its stability, selective precipitation, and versatile coordination chemistry make it an essential compound in both industrial and scientific contexts involving platinum.