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Dimethyl thio-toluene diamine
[CAS# 106264-79-3]

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Identification
Classification Pharmaceutical intermediate >> Heterocyclic compound intermediate >> Pyrimidine compound >> Amine
Name Dimethyl thio-toluene diamine
Synonyms 3,5-Dimethylthio-2,4-toluenediamine; 2,4-Diamino-3,5-dimethylthiotoluene
Molecular Structure CAS # 106264-79-3, Dimethyl thio-toluene diamine, 3,5-Dimethylthio-2,4-toluenediamine, 2,4-Diamino-3,5-dimethylthiotoluene
Molecular Formula C9H14N2S2
Molecular Weight 214.34
CAS Registry Number 106264-79-3
EC Number 600-731-0
SMILES S(c1c(c(cc(SC)c1N)C)N)C
Properties
Density 1.206±0.1 g/cm3, Calc.*
Index of Refraction 1.659, Calc.*
Boiling Point 318.1±42.0 ºC (760 mmHg), Calc.*, 200 ºC (1.68 mmHg)
Flash Point 146.2±27.9 ºC, Calc.*
* Calculated using Advanced Chemistry Development (ACD/Labs) Software.
Safety Data
Hazard Symbols symbol   GHS06 Danger    Details
Hazard Statements H301-H311-H331    Details
Precautionary Statements P261-P264-P270-P271-P280-P302+P352-P304+P340-P310-P330-P361-P403+P233-P405-P501    Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Chronic hazardous to the aquatic environmentAquatic Chronic1H410
Acute hazardous to the aquatic environmentAquatic Acute1H400
Acute toxicityAcute Tox.4H302
Skin sensitizationSkin Sens.1H317
SDS Available
up Discovory and Applicatios
Dimethyl thio-toluene diamine (DMTDA) is a chemical compound that has become important in industrial applications due to its role as a curing agent in polyurethane elastomers, coatings, and adhesives. Known for its ability to enhance mechanical properties, chemical resistance, and thermal stability, DMTDA plays a key role in industries requiring durable and high-performance materials. Its discovery and development are rooted in the search for safer and more efficient alternatives to other aromatic diamines, particularly methylene dianiline (MDA), which, while effective, raised concerns due to toxicity.

DMTDA is an aromatic diamine with sulfur-containing groups that make it highly reactive in curing processes. The compound was developed through research aimed at improving polyurethane elastomer performance while addressing safety and handling issues associated with other curing agents. The incorporation of sulfur atoms in the molecular structure of DMTDA facilitates faster cross-linking reactions in polyurethane, resulting in shorter curing times and improved mechanical properties. This has made it a popular choice in applications where both performance and production efficiency are critical.

Polyurethane elastomers cured with DMTDA are known for their superior tensile strength, resistance to abrasion, and durability in harsh environments. These properties make them essential in industries such as automotive, where materials are exposed to extreme conditions, including high stress, temperature variations, and chemical exposure. DMTDA-cured elastomers are used in components like seals, gaskets, and protective coatings, ensuring long-term reliability in critical automotive systems.

In addition to its widespread use in elastomers, DMTDA is also employed in the formulation of high-performance coatings. These coatings provide surfaces with enhanced resistance to mechanical wear and corrosion, particularly in industrial and marine environments where exposure to chemicals and physical stress is common. DMTDA’s sulfur-containing structure imparts excellent chemical resistance to these coatings, protecting surfaces from damage caused by solvents, oils, and acids. This makes DMTDA an essential ingredient in coatings for pipelines, tanks, and other infrastructure that are regularly subjected to corrosive substances.

Another important application of DMTDA is in adhesives, where it helps create strong and durable bonds in materials used in sectors such as aerospace, construction, and electronics. Adhesives cured with DMTDA offer superior resistance to environmental factors, ensuring that the bonded materials maintain their integrity over time, even in challenging conditions. This makes them ideal for use in structural bonding, electronic components, and high-performance engineering applications.

The environmental and safety profile of DMTDA is another factor that has contributed to its popularity in industrial applications. Compared to earlier aromatic diamines like MDA, DMTDA has a lower toxicity and poses fewer risks during handling, making it a safer option for workers in manufacturing settings. Additionally, DMTDA is often used in formulations designed to meet modern environmental standards, with ongoing research focused on developing more sustainable processes and products that incorporate this versatile chemical.

Dimethyl thio-toluene diamine has become an indispensable compound in the production of polyurethane elastomers, coatings, and adhesives due to its ability to improve material performance while offering safer handling and environmental advantages. Its discovery marked a significant advancement in industrial chemistry, providing a solution that meets the growing demand for high-performance, durable materials across a range of industries. As research into its applications continues, DMTDA will likely remain a key component in the development of next-generation materials.
Market Analysis Reports
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