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Tungsten hexachloride
[CAS# 13283-01-7]

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Complete supplier list of Tungsten hexachloride
Identification
Classification Inorganic chemical industry >> Inorganic salt >> Metal halides and halides >> Metal chlorides and salts
Name Tungsten hexachloride
Synonyms Tungsten(VI) chloride
Molecular Formula WCl6
Molecular Weight 396.56
CAS Registry Number 13283-01-7
EC Number 236-293-9
SMILES Cl[W](Cl)(Cl)(Cl)(Cl)Cl
Properties
Density 3.52
Melting point 275 ºC
Boiling point 347 ºC
Safety Data
Hazard Symbols symbol   GHS05 Danger    Details
Hazard Statements H314    Details
Precautionary Statements P260-P264-P280-P301+P330+P331-P302+P361+P354-P304+P340-P305+P354+P338-P316-P321-P363-P405-P501    Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Skin corrosionSkin Corr.1BH314
Specific target organ toxicity - single exposureSTOT SE3H335
Serious eye damageEye Dam.1H318
Substances or mixtures corrosive to metalsMet. Corr.1H290
Acute toxicityAcute Tox.4H302
Transport Information UN 3260
SDS Available
up Discovory and Applicatios
Tungsten hexachloride, with the chemical formula WCl₆, is a well-known compound in the field of inorganic chemistry. This substance was discovered in the early 20th century and has become a key reagent and catalyst in various chemical processes due to its unique properties.

The discovery of tungsten hexachloride can be traced back to advances in the synthesis of transition metal chlorides. Tungsten is a dense metal with a high melting point that forms a variety of chlorides, with tungsten hexachloride being the most reactive one. It was originally synthesized by reacting tungsten metal with chlorine gas, a method that revealed its powerful chemical behavior.

Tungsten hexachloride is characterized by high reactivity and volatility. It is a yellow to brown solid that sublimates easily, making it useful in vapor phase processes. This property is particularly advantageous in chemical vapor deposition (CVD), where tungsten hexachloride is used to deposit tungsten films on substrates. These films are an integral part of the electronics industry, particularly in the manufacture of semiconductor devices and thin film transistors.

In addition to its role in CVD, tungsten hexachloride is used as a catalyst for various organic reactions. Its ability to coordinate with a variety of ligands makes it an effective catalyst for the synthesis of complex organic molecules. It is particularly useful in reactions involving carbonyl compounds and in the formation of organometallic compounds. The compound's high oxidation state and strong Lewis acidity contribute to its catalytic efficiency.

Tungsten hexachloride is also used in materials science for the production of tungsten-based materials with unique properties. These materials can be used in high-performance applications such as aerospace components and cutting tools, due to tungsten's outstanding hardness and high melting point.

The compound's role extends to inorganic chemistry research, where it is used to explore the reactivity and properties of transition metal chlorides. Research involving tungsten hexachloride has led to a better understanding of metal-chloride interactions and has facilitated the development of new synthetic methods.

Overall, tungsten hexachloride is a valuable chemical in both industrial and research settings. Its unique properties, including high reactivity and volatility, make it necessary for processes such as chemical vapor deposition and catalytic synthesis. As research and technology develop, the applications of tungsten hexachloride are expected to expand, further solidifying its importance in modern chemistry and materials science.
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