Tungsten hexacarbonyl
[CAS# 14040-11-0]

Identification

• Classification: Organic raw materials >> Organometallic compound >> Organic scandium, tantalum, thallium, tungsten, antimony, lanthanum, lead, vanadium, molybdenum, chromium, ytterbium, etc.
• Name: Tungsten hexacarbonyl
• Molecular Formula: C₆O₆W
• Molecular Weight: 351.91
• CAS Registry Number: 14040-11-0
• EC Number: 237-880-2
• SMILES: [W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

Properties

• Density: 2.65 g/mL(25 ºC)
• Melting point: 150 ºC
• Boiling point: 175 ºC
• Water solubility: insoluble

Safety Data

• Hazard Symbols: GHS06 Danger
• Hazard Statements: H301+H311+H331
• Precautionary Statements: P261-P264-P270-P271-P280-P301+P310-P302+P352-P304+P340-P311-P330-P361-P363-P403+P233-P405-P501

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Acute toxicity	Acute Tox.	3	H331
Acute toxicity	Acute Tox.	3	H301
Acute toxicity	Acute Tox.	3	H311
Chronic hazardous to the aquatic environment	Aquatic Chronic	4	H413
Acute toxicity	Acute Tox.	4	H302
Eye irritation	Eye Irrit.	2	H319
Skin irritation	Skin Irrit.	2	H315

• Transport Information: UN 3466

Discovory and Applicatios

Tungsten hexacarbonyl, with the chemical formula W(CO)₆, is an important organometallic compound known for its unique structure and diverse applications. This compound, a hexacarbonyl complex of tungsten, has played a significant role in advancing the field of coordination chemistry and has practical uses in various industrial and research settings.

The discovery of tungsten hexacarbonyl can be traced back to the early 20th century when chemists were exploring the chemistry of transition metal carbonyls. The synthesis of W(CO)₆ involves reacting tungsten metal with carbon monoxide under controlled conditions to produce this stable hexacarbonyl complex. The compound features a central tungsten atom coordinated by six carbon monoxide ligands in an octahedral arrangement. This structure imparts notable electronic and steric properties to the complex.

One of the primary applications of tungsten hexacarbonyl is in catalysis. The compound is used as a catalyst or catalyst precursor in various chemical reactions. For example, W(CO)₆ serves as a catalyst in hydroformylation reactions, where it facilitates the addition of carbon monoxide and hydrogen to olefins, resulting in the formation of aldehydes. The ability of tungsten hexacarbonyl to stabilize reactive intermediates and participate in multiple reaction pathways makes it a valuable tool in the synthesis of complex organic molecules.

In addition to its catalytic applications, tungsten hexacarbonyl is used in the production of tungsten-based materials. The compound can be decomposed to produce tungsten metal or tungsten carbides, which are utilized in high-performance materials and coatings. Tungsten and its compounds are known for their high melting points, hardness, and resistance to wear and corrosion, making them suitable for use in cutting tools, aerospace components, and other demanding applications.

Tungsten hexacarbonyl also serves as a model compound for studying metal-carbonyl interactions and bonding. The well-defined structure of W(CO)₆ provides valuable insights into the nature of metal-carbonyl bonding and the electronic effects of carbonyl ligands on transition metals. Researchers use this compound to explore fundamental principles of coordination chemistry and to develop new metal-carbonyl complexes with tailored properties.

Handling tungsten hexacarbonyl requires careful attention due to the toxicity of carbon monoxide. Proper safety measures, including working in well-ventilated areas and using appropriate protective equipment, are essential to prevent exposure to toxic fumes. Storage and handling procedures should follow established safety guidelines to ensure safe use in laboratory and industrial settings.

Ongoing research continues to explore new applications and optimize the properties of tungsten hexacarbonyl. Advances in organometallic chemistry and materials science are leading to the development of novel catalysts and materials based on this compound, with potential implications for various industrial and technological applications.

In summary, tungsten hexacarbonyl is an important organometallic compound with significant applications in catalysis, materials science, and the study of metal-carbonyl interactions. Its discovery and development have contributed to the field of chemistry, and continued research holds promise for discovering further uses and improvements.

References

2011. Excitation and dissociation of tungsten hexacarbonyl W(CO)6: Statistical and nonstatistical dissociation processes. The Journal of Chemical Physics. S. Martin, L. Chen, R. Br�dy, J. Bernard, G. Montagne, X. Zhu.
DOI: 10.1063/1.3523347

2015. Seaborgium's complex studies. Nature Chemistry. Christoph E. Düllmann.
DOI: 10.1038/nchem.2328

2009. Preparation of hydantoins by catalytic oxidative carbonylation of alpha-amino amides. The Journal of Organic Chemistry. Seth M. Dumbris, Delmy J. D�az, Lisa McElwee-White.
DOI: 10.1021/jo9016138