Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate
[CAS# 75482-18-7]

Identification

• Classification: Organic raw materials >> Organic phosphine compound
• Name: Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate
• Synonyms: Sulfonium diphenyl[(phenylthio)phenyl] hexafluorophosphate
• Molecular Formula: C₂₄H₁₉S₂^.F₆P
• Molecular Weight: 516.50
• CAS Registry Number: 75482-18-7
• EC Number: 690-403-3
• SMILES: C1=CC=C(C=C1)SC2=CC=CC=C2[S+](C3=CC=CC=C3)C4=CC=CC=C4.F[P-](F)(F)(F)(F)F

Safety Data

• Hazard Symbols: GHS07 Warning
• Hazard Statements: H302-H315-H319-H335
• Precautionary Statements: P280-P305+P351+P338

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Eye irritation	Eye Irrit.	2	H319
Skin irritation	Skin Irrit.	2	H315

Discovory and Applicatios

Diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate is a chemical compound belonging to the family of sulfonium salts, which are widely used as photoinitiators in various polymerization processes. Its ability to generate reactive species upon exposure to UV light makes it a key component in industries that rely on UV-curable coatings, adhesives, and printing technologies.

The discovery of sulfonium salts, including diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate, emerged from research into photoinitiation mechanisms in the mid-20th century. These compounds demonstrated exceptional efficiency in initiating polymerization reactions when exposed to light. The structure of this compound is characterized by a sulfonium center bonded to three aryl groups—two phenyl groups and one phenylthio group—while the hexafluorophosphate serves as a counterion. This combination allows for excellent solubility in a variety of organic solvents and high stability, both of which are crucial for industrial applications.

One of the primary applications of diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate is in the formulation of UV-curable materials. In this context, the compound acts as a photoinitiator, absorbing UV light and generating reactive species that trigger polymerization. This capability is especially important in the production of fast-curing coatings and adhesives, which are used in industries such as automotive, electronics, and packaging. The compound is highly effective in initiating the cationic polymerization of epoxy resins and other monomers, resulting in durable, chemically resistant coatings.

In addition to its role in UV-curable systems, diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate finds application in advanced lithography processes, particularly in the semiconductor industry. As a photoinitiator, it helps create fine patterns on photoresist materials used in microchip production. The precise control of polymerization reactions enables the manufacture of intricate electronic components, contributing to the advancement of microelectronics and nanotechnology.

The compound is also employed in 3D printing technologies, specifically in stereolithography (SLA). SLA relies on photoinitiators to cure layers of liquid photopolymer resin into solid structures. The efficiency of diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate in generating reactive species ensures accurate polymerization, enabling the creation of detailed 3D-printed objects used in prototyping and manufacturing.

Despite its advantages, diphenyl[(phenylthio)phenyl]sulfonium hexafluorophosphate, like other sulfonium salts, poses challenges in terms of handling and environmental impact. The presence of the hexafluorophosphate anion, a fluorinated compound, raises concerns about its environmental persistence and potential health risks. As a result, researchers are investigating alternative anions and more sustainable photoinitiator systems to address these concerns while maintaining the compound's performance.