Platinum tetrakis(pentafluorophenyl)porphyrin
[CAS# 109781-47-7]

Identification

• Classification: Organic raw materials >> Organometallic compound >> Organic hafnium, mercury, silver, platinum, etc.
• Name: Platinum tetrakis(pentafluorophenyl)porphyrin
• Synonyms: Pt(II) meso-Tetra(pentafluorophenyl)porphine; meso-5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinatoplatinum
• Molecular Formula: C₄₄H₈F₂₀N₄Pt
• Molecular Weight: 1167.61
• CAS Registry Number: 109781-47-7
• EC Number: 844-206-6
• SMILES: C1=CC2=C(C3=NC(=C(C4=CC=C([N-]4)C(=C5C=CC(=N5)C(=C1[N-]2)C6=C(C(=C(C(=C6F)F)F)F)F)C7=C(C(=C(C(=C7F)F)F)F)F)C8=C(C(=C(C(=C8F)F)F)F)F)C=C3)C9=C(C(=C(C(=C9F)F)F)F)F.[Pt+2]

Safety Data

• Hazard Symbols: GHS07;GHS08 Warning
• Hazard Statements: H302+H312+H332-H315-H319-H361
• Precautionary Statements: P501-P261-P270-P202-P201-P271-P264-P280-P308+P313-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330-P302+P352+P312-P304+P340+P312-P405

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Specific target organ toxicity - single exposure	STOT SE	3	H335
Skin irritation	Skin Irrit.	2	H315
Eye irritation	Eye Irrit.	2	H319

Discovory and Applicatios

Platinum tetrakis(pentafluorophenyl)porphyrin is a platinum-based metalloporphyrin complex known for its distinctive photophysical and electronic properties. The discovery of this compound stems from extensive research into porphyrin derivatives and their potential as functional materials. Porphyrins, with their conjugated macrocyclic structure, have long been studied for their ability to coordinate various metals. The introduction of pentafluorophenyl groups enhances the compound’s electron-withdrawing characteristics, providing new avenues for application in fields such as photonics and sensing.

The synthesis of platinum tetrakis(pentafluorophenyl)porphyrin typically involves the reaction of platinum salts, such as platinum(II) acetylacetonate, with free-base tetrakis(pentafluorophenyl)porphyrin under reflux conditions. This metallation process yields a complex where the platinum ion is centrally coordinated within the porphyrin ring. The presence of pentafluorophenyl substituents increases the stability of the complex and modulates its electronic properties. The final product is characterized using techniques such as UV-Vis spectroscopy, nuclear magnetic resonance (NMR), and X-ray crystallography.

This compound has significant applications in oxygen sensing and optoelectronics. Platinum tetrakis(pentafluorophenyl)porphyrin exhibits strong phosphorescence, particularly under low-oxygen conditions, making it an ideal candidate for oxygen sensors in medical and industrial environments. Its long-lived phosphorescence allows accurate detection of oxygen concentrations, useful for monitoring biological tissues and environmental samples. In addition, the compound’s photostability and tunable emission properties enable its use in organic light-emitting diodes (OLEDs) and photodynamic therapy.

The introduction of pentafluorophenyl groups also facilitates the compound’s solubility in organic solvents, expanding its potential for use in solution-based applications. Researchers continue to explore its utility in energy conversion, molecular electronics, and as a catalyst in organic synthesis. The unique combination of platinum’s coordination chemistry and the porphyrin framework ensures that platinum tetrakis(pentafluorophenyl)porphyrin remains a versatile tool in modern scientific research.