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Titanium dimethylamide
[CAS# 3275-24-9]

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Complete supplier list of Titanium dimethylamide
Identification
Classification Organic raw materials >> Organometallic compound >> Organic titanium
Name Titanium dimethylamide
Synonyms Titanium tetrakis(dimethylamide); Tetrakis(dimethylamino)titanium
Molecular Structure CAS # 3275-24-9, Titanium dimethylamide, Titanium tetrakis(dimethylamide), Tetrakis(dimethylamino)titanium
Molecular Formula C8H24N4Ti
Molecular Weight 224.17
CAS Registry Number 3275-24-9
EC Number 221-904-3
SMILES C[N-]C.C[N-]C.C[N-]C.C[N-]C.[Ti+4]
Properties
Density 0.947
Boiling point 50 ºC (0.5 mmHg)
Flash point -5 ºC
Safety Data
Hazard Symbols symbol symbol symbol   GHS02;GHS05;GHS06'GHS07 Danger    Details
Hazard Statements H225-H260-H302+H332-H302-H314-H318-H331-H332    Details
Precautionary Statements P210-P223-P231+P232-P233-P240-P241-P242-P243-P260-P261-P264-P264+P265-P270-P271-P280-P301+P317-P301+P330+P331-P302+P335+P334-P302+P361+P354-P303+P361+P353-P304+P340-P305+P354+P338-P316-P317-P321-P330-P363-P370+P378-P402+P404-P403+P233-P403+P235-P405-P501    Details
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Flammable liquidsFlam. Liq.2H225
Skin corrosionSkin Corr.1BH314
Substances or mixtures which in contact with water emit flammable gasesWater-react.1H260
Acute toxicityAcute Tox.4H302
Acute toxicityAcute Tox.3H331
Serious eye damageEye Dam.1H318
Acute toxicityAcute Tox.4H332
Transport Information UN 3398
SDS Available
up Discovory and Applicatios
Titanium dimethamide, with the chemical formula Ti(NMe2)2, is an organotitanium compound that plays an important role in materials science and chemical synthesis. This compound, which has a titanium atom coordinated by two dimethamide groups, has attracted much attention due to its unique chemical properties and wide range of applications.

The discovery of titanium dimethamide is associated with the advancement of transition metal amide chemistry. The synthesis of Ti(NMe2)2 involves the reaction of titanium tetrachloride with dimethylamine to form this dimethamide complex. The structure of this compound generally features a titanium center and two dimethamide ligands arranged in a geometric shape that imparts specific reactivity and stability characteristics.

One of the main applications of titanium dimethamide is in the field of chemical vapor deposition (CVD). The compound can be used as a precursor for the deposition of titanium-based thin films and coatings. These films are essential for a variety of applications in electronics and materials engineering, where properties such as titanium's high strength and corrosion resistance are advantageous. Ti(NMe2)2 is able to form high-quality titanium films, thereby improving the performance and durability of electronic devices, including semiconductors and sensors.

In addition to its role in CVD, titanium dimethamide is used as a catalyst or catalyst precursor in chemical reactions. The compound can facilitate a variety of transformations, including polymerization and cross-coupling reactions. Its ability to stabilize reaction intermediates and facilitate specific chemical processes makes it a valuable tool in both industrial and research settings. The unique electronic and stereogenic properties of Ti(NMe2)2 allow for increased effectiveness as a catalyst in a variety of chemical applications.

Titanium dimethamide has also been used to study transition metal amides and their interactions with other ligands. Researchers have used this compound to gain insight into how titanium behaves in different chemical environments and to develop new materials with tailored properties. The knowledge gained from studying Ti(NMe2)2 has enhanced the understanding of coordination chemistry and the design of advanced materials for a variety of applications.

Due to the reactive nature of titanium dimethamide and the potential for association with dimethamide groups, standard safety precautions need to be taken when handling titanium dimethamide. Proper safety practices, including the use of personal protective equipment and working in well-ventilated areas, are essential to ensure safe handling and storage of this compound.

Ongoing research continues to explore new applications and improve the use of titanium dimethamide in different fields. Advances in materials science, catalysis, and thin-film technology are expected to expand the use of this compound and lead to further innovations.

In summary, titanium dicarbonamide is an important organotitanium compound with important applications in chemical vapor deposition, catalysis, and research. Its discovery and development have led to advances in materials science and chemical processes, and continued research is expected to reveal more uses and improvements.
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