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Polysiloxanes di-Me 3-hydroxypropyl Me ethoxylated
[CAS# 68937-54-2]

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Identification
Classification Catalysts and additives >> Polymer
Name Polysiloxanes di-Me 3-hydroxypropyl Me ethoxylated
Synonyms Silsurf D 208; Silsurf D 212CG; Silwet FZ 2171; Silwet L 7608; Tegopren 5842; X 22-6551
Molecular Structure CAS # 68937-54-2, Polysiloxanes di-Me 3-hydroxypropyl Me ethoxylated, Silsurf D 208, Silsurf D 212CG, Silwet FZ 2171, Silwet L 7608, Tegopren 5842, X 22-6551
CAS Registry Number 68937-54-2
EC Number 614-822-8
SMILES COCCOCCC[Si](C)(OC)O[Si](C)(C)C
Properties
Density 0.9±0.1 g/cm3 Calc.*
Boiling point 241.7±20.0 ºC 760 mmHg (Calc.)*
Flash point 86.7±22.2 ºC (Calc.)*
Index of refraction 1.418 (Calc.)*
* Calculated using Advanced Chemistry Development (ACD/Labs) Software.
Safety Data
Hazard Classification
up    Details
HazardClassCategory CodeHazard Statement
Eye irritationEye Irrit.2H319
Skin irritationSkin Irrit.2H315
Specific target organ toxicity - single exposureSTOT SE3H335
Acute toxicityAcute Tox.4H332
Chronic hazardous to the aquatic environmentAquatic Chronic3H412
Chronic hazardous to the aquatic environmentAquatic Chronic2H411
up Discovory and Applicatios
Polysiloxanes di-Me 3-hydroxypropyl Me ethoxylated are a class of modified silicone polymers characterized by a backbone of repeating siloxane (Si–O–Si) units with methyl (–CH3) and 3-hydroxypropyl substituents, further functionalized through ethoxylation. The general structure consists of alternating silicon and oxygen atoms forming the polymer chain, with di-methyl groups providing hydrophobicity, 3-hydroxypropyl groups offering sites for hydrogen bonding, and ethoxylated segments enhancing water solubility and surface activity.

The development of ethoxylated polysiloxanes traces back to the mid-20th century, following the discovery of polydimethylsiloxane (PDMS) and its derivatives. PDMS was widely recognized for its flexibility, thermal stability, and chemical inertness. To expand its application range, chemists introduced functional groups such as hydroxyalkyl or ethoxylated chains, creating amphiphilic materials capable of interfacing with both hydrophobic and hydrophilic environments. The ethoxylation step, which attaches short polyethylene oxide chains to the hydroxypropyl groups, improves dispersibility in aqueous systems and reduces surface tension, making these polymers useful as surfactants, emulsifiers, and wetting agents.

Applications of polysiloxanes di-Me 3-hydroxypropyl Me ethoxylated are broad and span cosmetics, pharmaceuticals, and industrial formulations. In personal care products, they are used as conditioning agents in hair care products, imparting smoothness, shine, and manageability while reducing static and frizz. The amphiphilic nature allows them to form thin, flexible films on hair or skin, providing long-lasting conditioning effects without greasiness. In skin care, these polymers function as emollients, moisturizers, and stabilizers in creams and lotions, enhancing texture and spreading properties.

In pharmaceuticals, these modified polysiloxanes can serve as excipients, stabilizing active ingredients in emulsions, creams, or gels. Their biocompatibility, flexibility, and surface-active properties allow controlled release of drugs and improved formulation stability.

Industrial uses include their role as surfactants, dispersants, and lubricants. The combination of hydrophobic siloxane chains and hydrophilic ethoxylated segments allows them to stabilize emulsions, improve wetting on surfaces, and reduce friction in processing equipment. They are particularly valuable in coatings, paints, and adhesives, where control of surface tension and spreading behavior is critical.

Overall, polysiloxanes di-Me 3-hydroxypropyl Me ethoxylated represent a versatile class of functional silicones that combine the inherent stability and flexibility of siloxanes with tailored amphiphilic properties. Their tunable balance of hydrophobic and hydrophilic segments has made them essential ingredients in modern personal care, pharmaceutical, and industrial formulations, providing performance advantages in film formation, conditioning, emulsification, and surface modification.
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