N-Nitroso-N-phenylhydroxylamine aluminum salt
[CAS# 15305-07-4]

Identification

• Classification: Organic raw materials >> Organometallic compound >> Organic aluminum
• Name: N-Nitroso-N-phenylhydroxylamine aluminum salt
• Synonyms: Tris(N-nitroso-N-phenylhydroxylamine) aluminum salt
• Molecular Formula: C₁₈H₁₅AlN₆O₆
• Molecular Weight: 438.33
• CAS Registry Number: 15305-07-4
• EC Number: 239-341-7
• SMILES: C1=CC=C(C=C1)/[N+](=N/[O-])/[O-].C1=CC=C(C=C1)/[N+](=N/[O-])/[O-].C1=CC=C(C=C1)/[N+](=N/[O-])/[O-].[Al+3]

Properties

• Melting point: 167-170 ºC

Safety Data

• Hazard Symbols: GHS07;GHS08;GHS09 Danger
• Hazard Statements: H302-H317-H350-H400-H410
• Precautionary Statements: P203-P261-P264-P270-P272-P273-P280-P301+P317-P302+P352-P318-P321-P330-P333+P317-P362+P364-P391-P405-P501

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Carcinogenicity	Carc.	1B	H350
Acute toxicity	Acute Tox.	4	H302
Skin sensitization	Skin Sens.	1B	H317
Chronic hazardous to the aquatic environment	Aquatic Chronic	1	H410
Acute hazardous to the aquatic environment	Aquatic Acute	1	H400
Germ cell mutagenicity	Muta.	2	H341
Serious eye damage	Eye Dam.	1	H318

Discovory and Applicatios

N-Nitroso-N-phenylhydroxylamine aluminum salt, also known by its systematic name, is a compound with specialized applications in both organic synthesis and industrial processes. This chemical substance, with the molecular formula C6H6N2O•Al, is derived from the reaction of N-nitroso-N-phenylhydroxylamine with an aluminum salt. It features a complex structure incorporating both nitroso and hydroxylamine groups coordinated with aluminum.

The discovery of N-nitroso-N-phenylhydroxylamine aluminum salt can be traced back to advancements in coordination chemistry and the study of nitroso compounds. The preparation of this compound typically involves the reaction of N-nitroso-N-phenylhydroxylamine with aluminum salts, such as aluminum chloride or aluminum sulfate, in a suitable solvent. The resulting compound is characterized by its aluminum coordination, which imparts unique properties compared to its non-metallic counterparts.

One of the primary applications of N-nitroso-N-phenylhydroxylamine aluminum salt is in the field of organic synthesis. The compound serves as a valuable reagent in various chemical transformations due to its nitroso and hydroxylamine functionalities. For example, it is utilized in the synthesis of nitroso derivatives and as a precursor for further chemical modifications. Its reactivity in nitrosation and hydroxylation reactions makes it an important tool for chemists working with complex organic molecules.

In addition to its role in organic synthesis, N-nitroso-N-phenylhydroxylamine aluminum salt is employed in materials science, particularly in the development of specialty polymers and advanced materials. The aluminum coordination in the compound contributes to its ability to interact with other chemical species, leading to the formation of unique polymer structures with enhanced properties. This application is of interest in the production of high-performance materials used in various industrial applications.

The compound also finds use in catalysis, where it acts as a catalyst in specific reactions due to its metal-ligand coordination. The aluminum center provides catalytic activity that can facilitate reactions involving nitroso and hydroxylamine groups. This catalytic property is leveraged in synthetic chemistry to improve reaction efficiency and selectivity.

Despite its beneficial applications, handling N-nitroso-N-phenylhydroxylamine aluminum salt requires adherence to safety protocols. As a nitroso compound with potential reactivity, it is essential to handle the substance with care and use appropriate protective measures to avoid exposure.

Overall, N-nitroso-N-phenylhydroxylamine aluminum salt is a significant compound in organic synthesis, materials science, and catalysis. Its unique chemical structure and properties make it a versatile reagent and catalyst in various chemical processes and applications.