Tin tetrachloride
[CAS# 7646-78-8]

Identification

• Classification: Organic raw materials >> Organometallic compound >> Organotin
• Name: Tin tetrachloride
• Synonyms: Tin(IV) chloride; Tetrachloro-stannane; Stannic chloride
• Molecular Formula: SnCl₄
• Molecular Weight: 260.50
• CAS Registry Number: 7646-78-8
• EC Number: 231-588-9
• SMILES: Cl[Sn](Cl)(Cl)Cl

Properties

• Density: 2.226
• Melting point: -33 ºC
• Index of Refraction: 1.512
• Boiling point: 114 ºC
• Water solubility: reacts

Safety Data

• Hazard Symbols: GHS05;GHS07;GHS08 Danger
• Hazard Statements: H315-H317-H318-H361-H373
• Precautionary Statements: P203-P260-P261-P264-P264+P265-P272-P280-P302+P352-P305+P354+P338-P317-P318-P319-P321-P332+P317-P333+P317-P362+P364-P405-P501

Hazard Classification

Hazard	Class	Category Code	Hazard Statement
Skin corrosion	Skin Corr.	1B	H314
Chronic hazardous to the aquatic environment	Aquatic Chronic	3	H412
Serious eye damage	Eye Dam.	1	H318
Specific target organ toxicity - single exposure	STOT SE	3	H335
Aspiration hazard	Asp. Tox.	1	H304

• Transport Information: UN 1827

Discovory and Applicatios

Tin tetrachloride, with the chemical formula SnCl₄, is an inorganic compound notable for its diverse applications in various fields, including organic synthesis, catalysis, and materials science. This colorless, hygroscopic liquid was first synthesized in the early 19th century, with its discovery attributed to the chemist Jöns Jacob Berzelius in 1823. The synthesis of tin tetrachloride involves the reaction of tin metal with chlorine gas, yielding a compound that showcases tin's ability to form stable halides.

The unique properties of tin tetrachloride stem from its Lewis acidic behavior, making it a versatile reagent in organic chemistry. As a strong electrophile, SnCl₄ is widely used as a catalyst for Friedel-Crafts reactions, which are essential in the synthesis of aromatic compounds. In these reactions, SnCl₄ facilitates the alkylation or acylation of aromatic hydrocarbons, significantly increasing reaction rates and improving yields. Its role in promoting electrophilic aromatic substitutions has established SnCl₄ as an indispensable tool in the pharmaceutical and fine chemical industries.

In addition to its role as a catalyst, tin tetrachloride is utilized in the preparation of organotin compounds, which have gained attention for their unique properties and applications. These organotin derivatives are valuable in the production of plastics, adhesives, and coatings, providing enhanced thermal stability and improved mechanical properties. Moreover, organotin compounds have been used as biocides in marine applications, although environmental concerns have led to increased scrutiny and regulation of their use.

Tin tetrachloride also finds application in materials science, particularly in the field of nanotechnology. Its ability to serve as a precursor for the deposition of tin oxide thin films makes it relevant in the production of electronic devices, sensors, and solar cells. The synthesis of tin oxide from SnCl₄ is often carried out via chemical vapor deposition techniques, leading to materials with excellent conductivity and optical properties.

Despite its numerous applications, tin tetrachloride must be handled with caution due to its corrosive nature and potential health hazards. It can cause severe burns upon contact with skin and is harmful if inhaled or ingested. As a result, appropriate safety measures are essential when working with this compound in industrial and laboratory settings.

In summary, tin tetrachloride is a significant inorganic compound with a rich history and diverse applications across chemistry and materials science. Its discovery paved the way for advancements in organic synthesis and the development of novel materials. Ongoing research continues to explore new applications and improve the safety and environmental aspects of using SnCl₄ in various industries.

References

2020. Facile synthesis of ZnO-SnO2 anchored ZIF-8 nanocomposite: a potential photocatalyst. Environmental Science and Pollution Research, 27(15).
DOI: 10.1007/s11356-020-08936-5

2014. Influence of Preferred Orientation on the Electrical Conductivity of Fluorine-Doped Tin Oxide Films. Scientific Reports, 4
DOI: 10.1038/srep03679

2017. Electrodeposition of SnO2 on FTO and its Application in Planar Heterojunction Perovskite Solar Cells as an Electron Transport Layer. Nanoscale Research Letters, 12
DOI: 10.1186/s11671-017-2247-x